%0 Book Section %T Rings Containing Arsenic, Antimony, or Bismuth %+ National Academy of Sciences of Ukraine (NASU) %+ Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux (IPREM) %A Romanenko, Vadim %A Sotiropoulos, Jean-Marc %B Comprehensive Heterocyclic Chemistry IV %I Elsevier %P 877-895 %8 2021 %D 2021 %R 10.1016/B978-0-12-409547-2.14857-7 %K A survey of the chemical literature published between 2008 and 2018 dealing with the synthesis %K structural investigations and chemical reactivity of seven-membered and larger rings containing arsenic %K antimony %K and bismuth is presented. The chapter outlines the advances in the chemistry of monocyclic %K fused and polycyclic species and should be read in conjunction with earlier chapters in CHEC II (1996 %K vol. 9 %K p. 971) and CHEC III (2008 %K vol. 14 %K p. 945). New routes to the synthesis of hypervalent cyclic diorganoantimony(III) and diorganobismuth(III) compounds of the general formula [X(CH2C6H4)2]MR (X=RN %K O %K S %K M=Sb %K Bi) and related heterocyclic systems are demonstrated. The reactivity and substituent modification procedures are covered. Also included are sections on theoretical methods and thermodynamic aspects such as aromaticity and thermodynamic stability. Applications of seven-membered and larger rings containing arsenic %K and bismuth in material and medicinal chemistry are discussed. %Z Chemical Sciences/Material chemistry %Z Chemical Sciences/Polymers %Z Chemical Sciences/Theoretical and/or physical chemistry %Z Chemical Sciences/Analytical chemistryBook sections %X A survey of the chemical literature published between 2008 and 2018 dealing with the synthesis, structural investigations and chemical reactivity of seven-membered and larger rings containing arsenic, antimony, and bismuth is presented. The chapter outlines the advances in the chemistry of monocyclic, fused and polycyclic species and should be read in conjunction with earlier chapters in CHEC II (1996, vol. 9, p. 971) and CHEC III (2008, vol. 14, p. 945). New routes to the synthesis of hypervalent cyclic diorganoantimony(III) and diorganobismuth(III) compounds of the general formula [X(CH2C6H4)2]MR (X=RN, O, S; M=Sb, Bi) and related heterocyclic systems are demonstrated. The reactivity and substituent modification procedures are covered. Also included are sections on theoretical methods and thermodynamic aspects such as aromaticity and thermodynamic stability. Applications of seven-membered and larger rings containing arsenic, antimony, and bismuth in material and medicinal chemistry are discussed. %G English %L hal-03906144 %U https://univ-pau.hal.science/hal-03906144 %~ CNRS %~ UNIV-PAU %~ IPREM %~ INC-CNRS %~ IPREM-CAPT %~ TEST2-HALCNRS