%0 Journal Article %T Germylene-β-sulfoxide Hemilabile Ligand in Coordination Chemistry %+ Laboratoire Hétérochimie Fondamentale et Appliquée (LHFA) %+ Institut de Chimie de Toulouse (ICT) %+ Institut des sciences analytiques et de physico-chimie pour l'environnement et les materiaux (IPREM) %A Lentz, Nicolas %A Cuevas-Chávez, Cynthia %A Mallet-Ladeira, Sonia %A Sotiropoulos, Jean-Marc %A Baceiredo, Antoine %A Kato, Tsuyoshi %A Madec, David %< avec comité de lecture %@ 0020-1669 %J Inorganic Chemistry %I American Chemical Society %V 60 %N 1 %P 423-430 %8 2021-01-04 %D 2021 %R 10.1021/acs.inorgchem.0c03101 %Z Chemical Sciences/Material chemistry %Z Chemical Sciences/Polymers %Z Chemical Sciences/Theoretical and/or physical chemistry %Z Chemical Sciences/Analytical chemistryJournal articles %X We describe herein the synthesis of a germylene-β-sulfoxide ligand, 1, and its abilities in coordination chemistry. Treatment of 1 with metal complexes [W(cod)(CO)4], [Mo(nbd)(CO)4] and [Ni(cod)2] afforded the corresponding (1)-chelated metal complexes (1)-W(CO)4 (2a), (1)-Mo(CO)4 (2b), and (1)-Ni(cod) (4a), clearly showing a bidentate ligation of the metal by the germanium(II) and sulfur centers. Coordination with [Ru(PPh3)3Cl2] afforded an unprecedented bridged bis-(ruthenium) complex 3b. In the case of 4a, the hemilability of the bidentate ligand 1 was demonstrated by sulfoxide substitution by a CO ligand. %G English %2 https://univ-pau.hal.science/hal-03113350/document %2 https://univ-pau.hal.science/hal-03113350/file/Inorg%20Chem%20manuscript-revised-08122020.pdf %L hal-03113350 %U https://univ-pau.hal.science/hal-03113350 %~ IRD %~ UNIV-TLSE3 %~ CNRS %~ UNIV-PAU %~ IPREM %~ INC-CNRS %~ IPREM-CAPT %~ TEST-HALCNRS %~ UPPA-OA %~ TOULOUSE-INP %~ UNIV-UT3 %~ UT3-INP %~ UT3-TOULOUSEINP %~ TEST2-HALCNRS %~ LHFA