The Kauzmann Transition to an Ideal Glass Phase - Multidisciplinary Institute in Artificial intelligence - Grenoble Alpes
Book Sections Year : 2023

The Kauzmann Transition to an Ideal Glass Phase

Abstract

The idea that a thermodynamic glass transition of some sort underlies the observedglass formation has been highly debated since Kauzmann first stressed the hypothet-ical entropy crisis that could take place if one were able to equilibrate supercooledliquids below the experimental glass transition temperature Tg . This a priori un-reachable transition at some TK < Tg has since received a firm theoretical basis as akey feature predicted by the mean-field theory of the glass transition. In this chapter,we assess whether, and in which form, such a transition can survive in finite dimen-sions, and we review some of the recent computer simulation work addressing theissue in 2- and 3-dimensional glass-forming liquid models. We also discuss theoreticalreasons to focus on an apparently inaccessible singularity.
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Dates and versions

hal-04491447 , version 1 (19-11-2024)

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Chiara Cammarota, Misaki Ozawa, Gilles Tarjus. The Kauzmann Transition to an Ideal Glass Phase. Patrick Charbonneau; Enzo Marinari; Giorgio Parisi; Federico Ricci-Tersenghi; Gabriele Sicuro; Francesco Zamponi; Marc Mezard. Spin Glass Theory and Far Beyond: Replica Symmetry Breaking after 40 Years, World Scientific Pub, pp.203-218, 2023, 978-9811273919. ⟨10.1142/9789811273926_0011⟩. ⟨hal-04491447⟩
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